Помогите осуществить превращения:
1. циклобутан (H2, Ni, t) → X1 (Cl2,
hν) → X2 (KOHспирт.)
→ X3 (Cl2) → X4 (Zn) → X5
2. CO2 + H2 (Ni, t) → X1 (Cl2, hν) → X2 (Na,t) → X3 (--2H2, Ni, t)
→ X4 (H2O, Hg2+)
→ X5
3. бутен-1 (HBr,
H2O2) → X1 (KOHспирт.) → X2 (Br2) → X3 (KOHспирт.) → X4 (Ag2O, NH3) → X5
4. C3H7COONa (NaOH, t) → X1 (--H2, Ni, t) → X2 (Br2) → X3 (KOHспирт.) → X4
(H2O, Hg2+) → X5
5. C2H4 (HCl) → X1 (Na, t) → X2 (AlCl3, t) → X3 (-H2, k, t) → X4 (H2O, H2SO4) → X5
1. циклобутан (H2, Ni, t) → X1 (Cl2,
hν) → X2 (KOHспирт.)
→ X3 (Cl2) → X4 (Zn) → X5
2. CO2 + H2 (Ni, t) → X1 (Cl2, hν) → X2 (Na,t) → X3 (--2H2, Ni, t)
→ X4 (H2O, Hg2+)
→ X5
3. бутен-1 (HBr,
H2O2) → X1 (KOHспирт.) → X2 (Br2) → X3 (KOHспирт.) → X4 (Ag2O, NH3) → X5
4. C3H7COONa (NaOH, t) → X1 (--H2, Ni, t) → X2 (Br2) → X3 (KOHспирт.) → X4
(H2O, Hg2+) → X5
5. C2H4 (HCl) → X1 (Na, t) → X2 (AlCl3, t) → X3 (-H2, k, t) → X4 (H2O, H2SO4) → X5
Answers & Comments
2.CO2 -H2/Ni-> CH4 -CL2/hv-> CH3Cl -Na/t-> C2H6 - -2H2/Ni-> C2H2 - H2O/Hg2+-> CH3CHO
3.CH2=CH-CH2-CH3 -HBr/H2O2-> СH2Br-CH2-CH2-CH3 -KOH/спирт> CH-C-CH2-CH3 -Ag2O, NH3-> CH3-CH2-C-C-Ag
4. C3H7COONa (NaOH, t) → C3H8 (--H2, Ni, t) →С3H6 (Br2) → C3H6Br2 (KOHспирт.) → C3H4 (H2O, Hg2+) → C2H5CHO